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2018 The Theoretical Description of the Erythromycin electrochemical determination, assisted by CoO(OH) – Poly(Acridine Orange) Composite

Erythromycin (Fig. 1)[1] is a bacteriostatic antibiotic macrolide produced by Streptomyces erythreus. Erythromycin A is considered its major active component. Erythromycin can be used to treat bacteria responsible for causing infections of the skin and upper respiratory tract, including Streptococcus, Staphylococcus, Haemophilus and Corynebacterium genera. Nevertheless, the administration of erythromycin includes the appearance of different side effects, such as diarrhea, nausea, abdominal pain, and vomiting, common, because erythromycin is a motilin agonist [2]. Thus, the development of the methods of its efficient and rapid sensing is really actual task.

International Symposium on Light Alloys and Composite Materials
UHAKS

Volodymyr V. Tkach Marta V. Kushnir Yana G. Ivanushko Sílvio C. de Oliveira Maryna M. Kornet Mykhailo P. Zavhorodnii Petro I. Yagodynets

259 186
Subject Area: Chemistry Broadcast Area: International Type: Oral Paper Language: English
2018 The Theoretical Description of the use of fumigatin as an electrode modifier

The use of chemically modified electrodes (CME) is a very important step in electroanalytical chemistry [1]. Compared to the bare electrodes, they have some advantages, like: - Rapidity; - Low cost; - Precisity; - Exactity; - Flexibility; - Versatility in use; - Affinity between the electrode modifier and the analyte. On the other hand, quinone-hydroquinonic redox system is one of the most abundant in nature and, at the same time, one of the most used as electrode modifiers in electroanalytical processes. For example, in [2], tetrachloro-o-quinone is used as a modifier for sulphite electrochemical determination. Yet, in [3], the quinone- hydroquinonic systems are present either in the electrode modifier or an analyte. It leeds to the possibility of use of natural hydroquinonic compounds, like fumigatin, natural colorant and antibiotic, as electrode modifiers. For now, no electroanalytical methods using fumigatin as electrode modifier have been developed. Nevertheless, from its chemical composition, it is possible to suggest that it would be possible, so, in this work, this possibility is theoretically analyzed. The electroanalytical process, in the case of the typical two-proton – two-electron transference, may be described as:

International Symposium on Light Alloys and Composite Materials
UHAKS

Volodymyr V. Tkach Marta V. Kushnir Petro I. Yagodynets

293 183
Subject Area: Chemistry Broadcast Area: International Type: Oral Paper Language: English